聚合物是通过化学键将小分子连接起来而形成的长链状大分子。由这种分子聚集形成的固体材料具有多层次的物质结构,这些结构会影响掺杂其中的各种功能基团的性质。本书将具有不同结构的稀土掺杂聚合物作为研究对象,从理论和实验的角度对这些聚合物进行了光谱分析、掺杂基质结构设计、发光性质与各层次结构的关系以及光量子调控等多方面的研究,包括各种新颖结构的设计和由其产生的各种特异性质。其中光量子调控是迅速发展的宽带通讯领域的关键技术,相应的基础和应用基础研究已形成一个由聚合物科学和光子学交叉而成的新兴学科——光子学聚合物科学。书中介绍的发光调控、三维光学存储和稀土掺杂聚合物光纤的光放大性质等均为光子学聚合物领域的最新进展。虽然本书是非常专业的学术专著,但是通过阅读,读者也能从中了解这一新兴交叉学科的概况。书中还列出了相关原始文献以满足感兴趣的读者进一步了解相关内容的需要。
Chapter 1Synthesis and characterizationof rare earth complex doped polymers
1.1Synthesis of rare earth complex doped polymer
1.2Uniformity and thermal stability of rare earth complex doped polymer
1.2.1X-ray diffraction of rare earth complex doped
1.2.2Near-field scanning analysis of rare earth complex doped
1.2.3Thermal properties of rare earth complex doped PMMA
Chapter 2Spectroscopic properties of rare earth complex doped PMMA and their Judd-Ofelt treatment
2.1The theory of spectroscopic analysis
2.1.1Energy level analysis and nephelauxetic effect of rare earth complexes
2.1.2Judd-Ofelt Theory
2.2Spectroscopic analysis of Nd(DBM)3Phen and Nd(DBM)3 (TPPO)2 in PMMA
2.2.1Energy level analysis and nephelauxetic effect of Nd(DBM)3Phen and Nd(DBM)3 (TPPO)2 in MMA and
2.2.2Radiative properties of Nd(DBM)3Phen and Nd(DBM)3 (TPPO)2 doped PMMA
2.3Spectroscopic analysis of Eu complexes in PMMA
2.3.1Fluorescence of Eu complexes in PMMAChapter 1Synthesis and characterizationof rare earth complex doped polymers
1.1Synthesis of rare earth complex doped polymer
1.2Uniformity and thermal stability of rare earth complex doped polymer
1.2.1X-ray diffraction of rare earth complex doped
1.2.2Near-field scanning analysis of rare earth complex doped
1.2.3Thermal properties of rare earth complex doped PMMA
Chapter 2Spectroscopic properties of rare earth complex doped PMMA and their Judd-Ofelt treatment
2.1The theory of spectroscopic analysis
2.1.1Energy level analysis and nephelauxetic effect of rare earth complexes
2.1.2Judd-Ofelt Theory
2.2Spectroscopic analysis of Nd(DBM)3Phen and Nd(DBM)3 (TPPO)2 in PMMA
2.2.1Energy level analysis and nephelauxetic effect of Nd(DBM)3Phen and Nd(DBM)3 (TPPO)2 in MMA and
2.2.2Radiative properties of Nd(DBM)3Phen and Nd(DBM)3 (TPPO)2 doped PMMA
2.3Spectroscopic analysis of Eu complexes in PMMA
2.3.1Fluorescence of Eu complexes in PMMA
2.3.2Radiative properties of Eu complexes in PMMA
2.4Spectroscopic analysis of Er complexes in PMMA
2.4.1Fluorescence of Er complexes in PMMA
2.4.2 Energy level analysis and nephelauxetic effect of Er(DBM)3 (TPPO)2 in PMMA
2.4.3Radiative properties of Er(DBM)3 (TPPO)2 doped PMMA
2.5Spectroscopic analysis of Pr complexes in PMMA
2.5.1Fluorescence of Pr complexes in PMMA
2.5:2Energy level analysis and Nephelauxetic effect of
Pr(DBM)3Phen and Pr(DBM)3 (TPPO)2 in PMMA
2.5.3Radiative properties of Pr(DBM)3 (TPPO)2 doped PMMA
2.6Spectroscopic analysis of Sm complexes in PMMA
2.6.1Fluorescent analysis of Sm complexes in MMA
2.6.2Energy level analysis and nephelauxetic effect of Sm(TTA)a (TPPO)2 in MMA and PMMA
2.6.3Radiative properties of Sm(DBM)a (TPPO)2 in MMA and PMMA
Chapter 3Rectification of excitation with bathochromic shift during emission measurement of Eu complexes
3.1Bathochromic shift during fluorescence measurement
3.2Theoretical model for treatment of Bathochromic shift
3.3Prediction of best exciting wavelength for fluorescence measurement
Chapter 4Fluorescence enhancing of rare earth complexes in PMMA
4.1Fluorescence enhancement of Eu(DBM)3Phen codoped with the other rare earth complexes in PMMA
4.2Fluorescence enhancement of Sm(DBM)3Phen codoped with other rare earth complexes in PMMA
4.3Model for luminescence enhancement in PMMA codoped with two kinds of rare earth complexes
4.3.1Intra-molecular energy transfer within each complex
4.3.2Inter-molecular energy transfer between complexes
4.3.3Quantitative model for luminescence enhancement of Eux Tby-PMMA
Chapter 5Effects of synergetic ligands on radiative properties of Eu(TTA)3 nL doped PMMA and LB films
5.1
7.1J-aggregates of rare earth complexes formed on the surface of silver nanoparticles<
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