配位化学(双语版) 第3版

Chapter 1 An Introduction to Coordination Chemistry
1.1 The History of Coordination Chemistry
1.1.1 The Origin of Coordination Chemistry
1.1.2 The Modern Coordination Chemistry—Werner Coordination Chemistry
1.1.3 Extending Coordination Chemistry—Supramolecular Chemistry
1.2 The Key Features of Coordination Complex
1.2.1 The Concepts of Coordination Complex
1.2.2 Classification of Ligand
1.2.3 Coordination Number and Coordination Geometry
1.2.4 Coordinative Unsaturation
1.2.5 Primary and Secondary Coordination Sphere
1.3 Nomenclature of Coordination Complex
1.4 Isomerism of Coordination Complex
1.4.1 Definition of Isomers
1.4.2 Structural (or Constitutional) Isomers
1.4.3 Stereoisomers
1.4.4 Supramolecular Isomerism
Chapter 2 The Symmetry and Bonding of Coordination Complex
2.1 Symmetry in Chemistry—Group Theory
2.1.1 Symmetry Elements
2.1.2 Symmetry Operation
2.1.3 Molecular Point Group
2.1.4 Character Tables
2.2 Valence Bond Theory
2.2.1 Hybridization of Atomic Orbitals
2.2.2 Molecular Shapes
2.3 Crystal Field Theory
2.3.1 CFT for Octahedral Geometry
2.3.2 CFT for Tetrahedral Geometry
2.3.3 CFT for Square Planar Geometry
2.3.4 Factors Influencing the Magnitude of
2.3.5 Applications of CFT
2.4 Molecular Orbital Theory
2.4.1 Molecular Orbital
2.4.2 Basic Rules of MO Theory
2.5 Intermolecular Interaction
2.5.1 Electrostatic Interactions
2.5.2 Hydrogen Bonding
2.5.3 π-π Stacking
2.5.4 Van de Waals Interactions
Chapter 3 Spectroscopy of Coordination Complex
3.1 Ultraviolet and Visible Absorption Spectroscopy (UV-Vis)
3.1.1 Electronic Transitions
3.1.2 Absorbing Species Containing π, σ and n Electrons
3.1.3 Electronic Absorption Spectrum of Coordination Complex
3.2 Infrared Spectroscopy and Raman Spectroscopy
3.2.1 Motion of Molecule
3.2.2 IR Spectroscopy of Coordination compound
3.2.3 The Raman Effect and Raman Scattering
3.2.4 Raman Selection Rules and Intensities
3.2.5 Polarization Effects
3.3 X-ray Diffraction Analysis
3.3.1 Symmetry in Crystals
3.3.2 Single Crystal X-ray Diffraction
3.3.3 Powder X-ray Diffraction
3.4 Photoelectron Spectroscopy
3.4.1 X-ray Photoelectron Spectroscopy (XPS)
3.4.2 Ultraviolet Photoelectron Spectroscopy (UPS)
3.5 Nuclear Magnetic Resonance (NMR) Spectroscopy
3.5.1 Basic Principle of NMR Spectroscopy
3.5.2 The Nuclear Absorption of Radiation in Magnetic Field
3.5.3 Chemical Shift
3.5.4 Spin-Spin Coupling
3.5.5 Some Chemical Shifts in 1H NMR and 13C NMR
3.6 Electron Paramagnetic Resonance (EPR)
3.7 Circular Dichroism (CD)
3.8 Advanced Imaging Techniques for Nanosize Coordination Complex
3.8.1 Electron Microscopies
3.8.2 Scanning probe microscopies
Chapter 4 The Structure and Physicochemical Properties of Coordination Complex
4.1 The Structures of Several Kinds of Coordination Complexes
4.1.1 Organometallic Complex
4.1.2 Cluster
4.1.3 Macrocyclic Complex and Bioinorganic Complex
4.1.4 Supramolecular Assemblies Containing Transition Metal Ions(Polynuclear Complex)
4.2 Thermodynamic Properties
4.2.1 Thermodynamic Stability
4.2.2 Stability of Complexes
4.2.3 Calculation of Species Concentrations
4.3 Molecular Electronic Devices—Redox-active Coordination Complex
4.3.1 Concept of Molecular Electronics
4.3.2 Molecular Wires
4.3.3 Molecular Switching
4.4 Magnetic Properties of Coordination Complex
4.4.1 Magnetic States of Material
4.4.2 Interaction with an External Magnetic Field
4.4.3 Diamagnetism
4.4.4 Paramagnetism
4.4.5 Ferromagnetism, Antiferromagnetism and Ferrimagnetism
4.4.6 Magnetic Behaviour of Variation with Temp

李晖，北京理工大学，教授，北京理工大学理学院化学系教授，博士生导师，中国化学会会员，美国化学会会员，欧美同学会会员，靠前和靠前等多个重要学术杂志论文的评审人。研究领域有三个方向：（1）配位化学；（2）超分子化学；（3）晶体结构。1997年南京大学配位化学国家重点实验室获博士学位。曾在中科院感光化学研究所、英国诺丁汉大学化学系（英国皇家学会王宽诚基金研究员）、台湾地区大学化学系及台湾地区中央研究院从事博士后研究。主持了多项国家自然科学基金；一项教育部高等学校博士点专项基金；一项教育部留学回国人员基金；北京理工大学基础研究基金以及靠前合作基金等多项科研项目。发表学术论文几十篇。主讲本科生、硕士生和博士生的学位课和专业选修课。双语讲授的“配位化学”为北京理工大学精品课程。出版了《配位化学（双语版）》教材（ISBN 7-5025-7996-6，化学工业出版社）。